Well the initial results were 'interesting'.
Firstly the coffee on the surface looked pretty similar to when it went in.
I sampled some, and this didn't dissolve any better than it had done before going in the oven, but still tastes like (instant) coffee.
There was another side effect though: -
I hadn't anticipated this, but apparently freeze-dried coffee had a melting point of slightly below 100
oC. The granules at the bottom had melted and reformed into a sort of bitumen-like substance. Once re-solidified the mixture was stuck pretty firmly, and due to the much lower surface/volume ratio it is now soaking in the sink while slowly dissolving in an excess of hot water (it's stuck firmly in the beaker at present).
I've sampled some of the matrial from that beaker with a spoon and the wet sample looks like this: -
Conclusions: -
1. Heating instant coffee does not make it dissolve any better
2. Coffee melts!
3. The resultant solidified material may be a suitable material for pot-hole repairs
Recommendations: -
1. Don't put instant coffee in the oven
2. The author should buy some more coffee