Do you "heel-shift" between rings?
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I think it's possible to heel shift from big ring to small; but not from small ring to big. I swapped the original
ring for a Shimano Dura Ace model; lost the pants/trouser protector in the process. Now when I shift; the chain
jumps off to the outside sometimes. It lands on the spider of the crank; I'm able to push the chain back using my
heel:
2013 Brompton DA chainring Ultegra chain by
1nterceptor, on Flickr
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I did something similar with a Spa cycles touring triple, but with the biggest ring replaced by a chain guard, giving me 28/38, on a 20t rear, on a sturmey archer 8 speed hub. It's pretty good at going up hills, but I was still defeated by the big climb up to Black hut on the Isle of Man TT. 417m of ascent was a killer...
J