They’re also, I believe, hollow, as at those elevated voltages the charge is mainly carried on the surface of the conductor.
AUIU they have a steel or composite core, which allows them to run hotter (ie. at higher current) than pure aluminium or copper without excessive sag. The skin effect is a function of frequency, not voltage.
Al 'cos lighter than Cu I would think.
Yep, you can increase the area of the conductor to the point where it has the same resistance as copper, and still win on weight, which means less expensive pylons.
(Personally, I get scared of anything higher than about 36 voles.)