just replaced the V-Brakes on No1 daughter's MTB with some Tektro 430's, front went on with no issues, adjusted nicely. Rear is a bit of an issue, the RHS arm (as you look from the rear) was harder to get off and very stiff to get the replacement onto the boss. It's also not moving freely, so will pull in with the lever, but is not springing out again.
My diagnosis is that the mounting boss is not straight and needs to be replaced?