I have/had 2 XACD ti frames, one Pinarello Ti frame, one trek 5500 carbon frame and one Look 585 Ultra (stiff)carbon frame (as well a carbon mtb, steel audax, alu cross)
The carbon frames, all of them, are without question faster than all the others (and the trek and the Pinarello have been built up with the same bits) so if you want speed, acceleration and climbing ability it has to be carbon.
Of the 2 carbon road frames the Trek makes a lovely audax bike. Did the brevet cymru on it a few weeks ago, will ride the BCM diy on it. Its the most comfortable of my bikes by far. It is a 'soft' carbon frame.
The Look 585 ultra is the lightest and stiffest frame I've ridden. I find it to be an excellent climbing frame as there is no discernable flex when out of the saddle, but.... I wouldn't want to be on it for anything longer than 200k... it will beat you up.
I've recently swapped the forks on the trek from the original ones to Columbus carve. Much much sharper handling, but also much more road buzz transmitted.
Thus... as has been said above, beware of generalisations, try before you buy.
(oh..and don't bother with steel)