Perhaps the GUI is lacking, if so the command line interface would be "virsh attach-disk".
Kim, you are very bad!
tim@Dalamar2:~$ virsh attach-disk win7 /dev/sr0 hdc --type cdromerror: Failed to attach diskerror: Requested operation is not valid: domain is not running
tim@Dalamar2:~$ virsh attach-disk win7 /dev/sr0 hdc --type cdromerror: Failed to attach diskerror: Operation not supported: cdrom/floppy device hotplug isn't supported
tim@Dalamar2:~$ groups timtim : tim adm cdrom sudo dip plugdev kvm lpadmin lxd sambashare libvirt
<disk type='block' device='disk'> <driver name='qemu' type='raw'/> <source dev='/dev/sdd'/> <target dev='vdb' bus='virtio'/> </disk>
<disk type='block' device='cdrom'> <driver name='qemu' type='raw'/> <source dev='/dev/sr0'/> <target dev='sdd' bus='sata'/> <readonly/> <shareable/> <address type='drive' controller='0' bus='0' target='0' unit='3'/></disk.