The battery of a smartphone in flight mode and used for the occasional photo will only drop to about 60% during the event. This is based on my Samsung Galaxy S2 on LEL2013.
Flight mode is indeed a useful feature. I was thinking about using my phone for live GPS tracking (via mapmytracks or glympse or somesuch) but maybe I won't. I don't know if anyone is going to care enough about following my live progress. And if they do, they will be able to see when I check in at controls on the website.
If not using dynamo or AA battery based lights and GPS then you'll need an external battery pack to guarantee charging where and when you need it. A quoted capacity of 10,000mAh will cover your GPS needs.
I used a 16,000mAh battery pack on WCW and it was more than enough to keep my GPS and phone topped up - or would have been if I'd remembered to plug in my Garmin at Chester.
It's also quite heavy and bulky (and doesn't fit in my top tube bag), and something smaller like 10,000mAh would be more convenient. I can get a good 300km out of my Edge 510 between charges. A bit of internet research suggests that the capacity of the 510's internal battery is 800mAh, and the iPhone 5S has a capacity of 1,570mAh, so even if I need to charge up both once per day, 10,000mAh should be plenty, especially if I keep a spare in my bag to swap at sleep stops. I don't know how much juice the Di2 will need to keep it topped up but it won't be much.
On LEL2013 I only topped up the GPS with the external battery pack when stopped at controls. I got away with two lipstick size 3,600mAh battery packs and starting with a fully charged GPS, but then I did turn off the GPS when stopped at controls
I tend to leave mine running at controls (with autopause off). It doesn't seem to make much difference to battery burn time - which I suspect is because turning it on and re-finding the satellites is a big drain. Although that only really applies to short stops. For longer (sleep) stops, turning it off would be sensible.
Anker are well known in this field.
Aye. The one I use at the moment is Anker and I'm very happy with it. Their cables are good too - the iPhone is very temperamental about which cables it works with but seems happy to let you use Anker ones.
If charging whilst navigating then your GPS may need a special cable depending on the model.
The Edge 510 doesn't seem to mind being charged while in use (using the cable that came with it). The only issue there will be the power source - if I go down the dynamo route, I'm guessing I'll still need a battery pack to ensure a consistent output.