An idea, but it would have to be severely hacked to disable the heater (and, to leave it working for emergency use in boiler failure scenario)
The main option would be to build something with an Arduino, which would typically be used for temperature control, but it is fascinating that there is no commercial product for something so widely used with substantial potential energy saving benefit.
In my experimenting to date, I have found that the mechanical thermostat (Honeywell) has a substantial dead zone, tuning up and down. That alone would be reason to go digital, each extra unnecessary degree costs ££.