Perfect, that all makes sense pcolbeck
We have in theory a slightly simpler system with an automatic wood pellet boiler and solar thermal and a large unvented cylinder. However, ours is a pressurised cylinder and the boiler primary circuit also runs at 1.5 to 2 bar which is a pain in the butt as our
utility plant room contains four expansion vessels - a small one onboard the boiler, a larger one for the central heating circuit, one for the glycol solar circuit and another for the 200+ litre hot water tank. However, this avoids an open vented expansion tank in the loft and a vent pipe right up through the house.
From experience, our solar thermal works well. However, winter contribution to the hot water is small although it will preheat the bottom half of the cylinder a bit on a good sunny winter day. Our immersion is half way up the tank so we can run our domestic hot water on either the immersion or the boiler, or solar only if it's sunny enough. Our boiler has fairly sophisticated controls which manage the solar too so it checks what the panels are doing against the current DHW temperature and programme time scheduled before deciding whether the boiler needs to kick-in which aids overall system efficiency.
I like the idea of a system than includes a wood burning stove too though for a bit of extra resilience for when the zombies come/post-Brexit (delete as applicable), although we do have a separate woodburner so when the boiler periodically conks out we can keep part of the house warmish and still have hot water from the immersion. Just need some PV and a Tesla Powerwall now (or at least one of these
https://myenergi.uk/product/eddi/ ), and we're ready for anything.
Regarding the OP (just to keep on topic a bit), the issue of differing hydraulic fluids can always be overcome by adding a suitable heat exchanger (plate, or shell and core) to provide separation.