I really must get around to writing up my blog from my LLC ride last year!
I rode on my 32 wheels but I should imagine 25mm should be fine with a couple of possible alterations.
The Old Coach Road section between Rhyader and Newbridge was probably the roughest part and which might get a bit shaky on 25s so following the alternative route along the main road there might be wise - not as pretty and possibly a bit busy but I did find thecoach road a bit rough on 32s
Actually there is just the one alteration as I rode S-N from Cardiff and the only other rough part was around Tal-y-Bont so if you head to Chepstow you'll avoid that. I actually did use roads along that section which was smooth but I think with a fair bit more climbing than on the forest tracks.
Time wise I did it in 3 full and 2 1/2 days - or 4 as it might also be called... First day was train to Cardiff and a half days ride starting at about 3pm. Then did 3 solid days to get me to Bangor and a final 1/2 day across Anglessey to get me to Bangor and a 2pm train home.
sizbut gives a pretty good account. I went off piste a bit around Harlech as the route doesnt go into the town and I could not countenance the idea of being that close to Harlech castle without visting so I followed the main road between Harlech and Porthmadog - but watch out for teh level crossing at Harlech - the track crosses the road at about 35-45 degress and I managed to get my wheel caught in the tracks!
The toughest bits are eith side of Mach; whether heading north or south. Heading North the climb out of Mach up from Aberllefenni was the toughest I've ever done and I will never forgive the false summit I came across 2/3 of the way up! Coming the other way that climb up to there on your way into Mach will also be pretty tough I should think. I can't comment on TEC's variation.
I reckon the climb out of Mach towards the Mach Mountain Pass will be pretty tough going - it was certainly a test on the brakes going the other way! Hope you get to see some of the views though - I was in constant cloud the whole day.
I gather the climb out of the Hay up onto the Gospel Pass might be a good climb as well. I had considered going out of my way to try and that as an extra; but let's just say that never happened....
I used the two Sustrans guides the whole way and they were excellent and the route was (mostly) well signed. If you're interested my strava sections (with pics) are on these links:
https://www.strava.com/activities/654444054https://www.strava.com/activities/655712013https://www.strava.com/activities/656646070https://www.strava.com/activities/657652177https://www.strava.com/activities/658322770