Does salbutamol have any effect on healthy people?
Yes, but it's a marginal gain, as it were. The effect of salbutamol on asthma can be positively spectacular.
Peak flow isn't the whole story (it can fluctuate randomly for some people, and means exactly nothing about how bad your asthma is unless you have an established baseline), but it's easy to test and plot graphs of, and may be a useful indication.
For me a change of 70l/min would be the point where the difference is meaningful, rather than random noise. But I have hobbit lungs and can achieve a peak flow of 630 odd on a good day, which is fairly high. (By the time I'm down in the mid 400s, there's definitely something wrong, but that might be considered a healthy reading by most people's standards.) I generally notice symptoms
[1] before there's an unambiguous change in my peak flow.
[1] Or someone who knows me well spots me subconsciously scratching my neck (a tell-tale habit), and brings it to my attention.