Most expansion vessels have a diaphragm with compressed air on one side and boiler water on the other.
If the compressed air leaks away (I don't know how) then your expansion vessel becomes a waste of space.
What you need to do is depressurise the system, often by opening a radiator bleed valve. Then find the filling valve on the expansion vessel, it's usually a Schrader valve. Pump the expansion vessel to 1 bar with air. Then close the bleed valve and pressurise the system with water as normal.
If there is no air in the expansion vessel, the pressure will vary more as the temperature changes. That can cause the pressure relief to let some water out when the water is hot, and the pressure is then too low when the system cools down.